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脂環(huán)族環(huán)氧樹脂在UV陽離子光固化中的應用
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更新日期： 2021-3-29 |
UV光固化技術是一種高效、環(huán)保、節(jié)能、優(yōu)質(zhì)的面向21世紀的新技術，廣泛應用于涂料、膠黏劑、油墨、光電子等領域。
UV curing technology is a high-efficiency, environmentally friendly, energy-saving, advanced technology in the 21st century, which is widely used in coatings, adhesives, inks, optoelectronics and other fields.
自1946年美國Inmont公司取得第一個UV光固化油墨專利、1968年德國Bayer公司開發(fā)了第一代UV光固化木器涂料以來，光固化涂料在全球獲得迅速發(fā)展。近幾十年來，一大批新型、高效的光引發(fā)劑、樹脂、單體和先進的UV光源被應用于UV光固化行業(yè)，促進了行業(yè)的發(fā)展。
Since the American Inmont company obtained the first UV curable ink patent in 1946, and the German Bayer Company developed the first generation of UV curable wood coatings in 1968, UV curable coatings have developed rapidly all over the world. In recent decades, a large number of new and efficient photoinitiators, resins, monomers and advanced UV light sources have been applied to the UV curing industry, which has promoted industry development.
脂環(huán)族環(huán)氧樹脂是含有兩個脂環(huán)環(huán)氧基的低分子化合物。其本身不是聚合物，但是與固化劑作用后能生成性能優(yōu)異的三維體型結構的聚合物。具有低粘度、熱穩(wěn)定性好、低鹵素含量和優(yōu)良電氣性能、耐紫外線耐黃變優(yōu)異、UV固化無氧阻聚、低遷移性等優(yōu)勢。
The cycloaliphatic epoxy resin is a low molecular compound containing two cycloaliphatic epoxy groups. It is not a polymer itself, but when reacting with the curing agent it can generate a polymer with excellent-performance three-dimensional structure. Advantages include low viscosity, good thermal stability, low halogen content, great electrical performance, excellent UV-resistant and non-yellowing performance, low migration and no oxygen inhibition after UV curing, etc.
主要的脂環(huán)族環(huán)氧樹脂
UV光固化油墨 / UV curable inks
UV光固化涂料 / UV curable coatings
2.1 UV光固化油墨篇 / UV curable inks
● 組成：UV樹脂，單聚物(通常在普通油墨作為溶劑，降粘，參與化學反應)，添加劑，光引發(fā)劑
● Composition: UV resin, monomer (used as solvent in ordinary ink for reduced viscosity), additive, photoinitiator
● 優(yōu)勢：低VOC, 無溶劑，干燥速度快，光澤度好，色彩鮮艷，耐水耐溶劑，耐磨
● Advantages: Low VOC, solvent free, fast drying speed, high gloss, brilliant color, strong resistance to moisture / solvent / abrasion.
● 應用領域 / Applications
UV油墨品種：UV研磨，UV冰凍，UV發(fā)泡，UV起皺，UV凸字，UV折光，UV點綴， UV上光油的特殊包裝印刷油墨。
UV ink varieties: UV grinding, UV freezing, UV foaming, UV wrinkling, UV lettering, UV refracting, UV decorating, UV varnishing when used for printing inks in special packaging.
UV油墨印刷技術：UV膠印油墨、UV絲印油墨、UV移印油墨、UV水性噴墨油墨。
UV ink printing technology: UV offset printing ink, UV screen printing ink, UV pad printing ink, UV water-based inkjet ink
UV油墨應用領域：UV印鐵油墨、UV金屬油墨、UV玻璃油墨、UV塑料油墨、UV電路版油墨、UV感光油墨。
UV ink application: UV tin printing ink, UV metallic ink, UV glass ink, UV plastic ink, UV circuit board ink, UV photosensitive ink
發(fā)展前景 / Prospects
UV光固化油墨適用于各種基材，可替代溶劑型油墨或水性油墨。
UV curable inks are suitable for various substrates. They can replace solvent-based inks or water-based inks.
全球UV光固化油墨市場將于2020年達到35億美元，2015-2020年間的復合年均增長率超過15.7%。由于包裝食品及飲料行業(yè)的增長帶動了標簽印刷需求的上升，成為UV油墨的主要增長領域。
The global UV curable ink market will reach 3.5 billion U.S. dollars in 2020, with a compound annual growth rate of more than 15.7% between 2015 and 2020. As the growth of the packaged food and beverage industry has driven the increase in demand for label printing, it has become a major growth area for UV inks.
2.2 UV光固化涂料 / UV curable coatings
● 組成：顏料/添料/助劑，光引發(fā)劑，活性稀釋劑，低聚物
● Composition: pigment/additive/auxiliary, photoinitiator, reactive diluent, oligomer
● 優(yōu)勢：固化快，低VOC，成本低，浪費少，節(jié)約能源，性能好(硬度高，耐磨好，透明度高，質(zhì)量好)
● Advantages: Fast curing, low VOC, low cost, less waste, energy saving, outstanding performance (high hardness, good abrasion resistance, high transparency, good quality)
● 應用 / Applications
木器涂料/wood coating：
家具、門窗、護墻板、地板、日常生活用品、木制樂器、體育用品、文具、兒童玩具
Furniture, doors and windows, wall panels, flooring, daily necessities, wooden musical instruments, sporting goods, stationery, children's toys
印刷材料 / printing material
高檔的香煙，化妝品，食品包裝等印刷材料
High-end printing materials for cigarettes, cosmetics, food packaging, etc.
塑料涂料 / plastic coating
手機、電視機、電腦、汽車、摩托車配件等領域
Mobile phones, TVs, computers, automobiles, motorcycle accessories and other fields
罩印清漆 / overprint varnish
涂于面漆之上形成保護裝飾圖層的清漆
Apply on top coat to form a varnish that protects the decorative layer.
光纖涂覆材料 / optical fiber coating material
保護光導玻璃纖維免受外界環(huán)境影響、保持其足夠的機械強度和光學性能的涂料
A coating that protects the optical glass fiber from the external environment and maintains its sufficient mechanical strength and optical performance
發(fā)展前景 / Prospects
UV光固化涂料在光纖涂層、木材、飲料罐、食品包裝、醫(yī)療器械和汽車行業(yè)中應用日趨成熟。
UV curable coatings are becoming more and more mature in different industries, such as optical fiber coatings, wood, beverage cans, food packaging, medical equipment and automotive industries.
預計全球UV固化涂料市場將從2020年的65億美元增長到2025年的114億美元，復合年增長率在預測期內(nèi)為12.0%。預計政府將著重采用清潔燃料以及自然和燃料電池電動汽車數(shù)量的增長來推動市場發(fā)展。
The global UV curing coatings market is expected to grow from USD 6.5 billion in 2020 to USD 11.4 billion in 2025, with a compound annual growth rate of 12.0% during the forecast period. The government is expected to focus on the adoption of clean fuels and the growth in the number of natural and fuel cell electric vehicles to promote market development.
關于3D打印篇和UV光固化膠黏劑篇，我們將在下期內(nèi)容中具體講解不同行業(yè)中的應用、技術參考和發(fā)展前景，大家千萬不要錯過哦~
Regarding 3D printing materials and UV curing adhesives, we will specifically explain their applications, technical references and development prospects in different industries in the next content. Don't miss it~
總結 Summary
當前，世界經(jīng)濟整體加速向低碳化深入發(fā)展，節(jié)能減排、綠色能源、可持續(xù)發(fā)展等逐漸成為世界各國關注的焦點。光固化材料在固化時非常快速且無溶劑揮發(fā)，大大降低了對環(huán)境的污染，近年來作為一種環(huán)境友好的綠色材料得到了蓬勃的發(fā)展，應用的范圍越來越廣。隨著高性能樹脂和光引發(fā)劑品種的增多，固化技術的不斷創(chuàng)新，光固化應用領域越來越多，為人們帶來了越來越多的優(yōu)質(zhì)的產(chǎn)品。
At present, global economy as a whole is accelerating towards low-carbon development. Energy conservation, emission reduction, green energy and sustainable development have gradually become the focus of every country around the world. UV-curing materials can provide very fast, solvent-free curing speed, which greatly reduces environmental pollution. In recent years, as an environmentally friendly green material, it has developed vigorously and has a wider range of applications. With the increase in the varieties of high-performance resins and photoinitiators, as well as the continuous innovation of curing technology, more and more UV curing applications have brought more and more high-quality products to people.
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